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Nitric Acid Plant

Brief Overview
 

Capacity:

 

315 Tons/Day

Technology:

 

GRANDE PAROISE
 

Built:

 

1979 Operated for three months (Test run only)
 

Products Produced:

 

Nitric Acid 62%

Documentation:

 

Available
 

Major Equipment:

 

Process
-
Dual Pressure

Pressure (Burner)
-
36 PSIG

Presure (Absorption)
-
102-110 PSIG

Steam Production
- 300 PSIG @ 400 C

NOX
-
106 PPM

Absorption Section
-
Two columns

Compressor
-
ELLIOT

Expander
-
ELLIOT
 


Process Description

Ammonia Oxidation - at a pressure level of 34 to 29 PSIG.
Ammonia and air, free from dust and oil, are mixed. The mixture of air and ammonia is introduced in a burner and dispersed over the platinum alloy catalyst gauze.

The velocity of the air/ammonia mixture is such as it assures the necessary turbulence for obtaining the most complete diffusion of gases possible on the catalyst, and a sufficient contact time to favor the production of nitrogen oxide.

Ammonia oxidation makes nitrogen oxide in contact with catalyst gauzes. It has been proposed that the catalyst operates as follows:
- Surface absorption of oxygen by the catalyst.
- Catalytic reaction of ammonia, perhaps by the hydroxylamine stage, to form the imide radical NH on the catalyst surface.
- Molecular oxygen reaction with the imide to produce nitrogen oxide and water.